Optimized bioleaching of spent FCC catalysts for the recovery of critical metals
Physicochemical Problems of Mineral Processing, cilt.62, sa.2, 2026 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 62 Sayı: 2
- Basım Tarihi: 2026
- Doi Numarası: 10.37190/ppmp/220335
- Dergi Adı: Physicochemical Problems of Mineral Processing
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Applied Science & Technology Source
- Anahtar Kelimeler: biohydrometallurgy, cerium, critical metals, lanthanum, spent fluid catalytic cracking catalysts
- Açık Arşiv Koleksiyonu: AVESİS Açık Erişim Koleksiyonu
- Sağlık Bilimleri Üniversitesi Adresli: Evet
Özet
Spent fluid catalytic cracking (FCC) catalysts, generated in large volumes by petroleum refining, represent a promising secondary source of critical metals such as lanthanum, cerium, titanium, and vanadium. In this study, a biohydrometallurgical approach was applied to recover these metals using Acidithiobacillus ferrooxidans and Leptospirillum ferrooxidans. The spent FCC catalyst, supplied by petroleum refinery, was characterized through WD-XRF, XRD, SEM-EDS, and ICP-OES analyses, confirming significant concentrations of La2O3 (1.44%), TiO2 (1.43%), and CeO2 (0.23%). Bioleaching experiments were conducted under varying initial ferrous ion concentrations (1–9 g/L) and pulp densities (5–20% w/v) at 35°C over 14 days. Results revealed that the optimal conditions for maximum recovery occurred at 5 g/L Fe2+ and 10% pulp density, achieving leaching efficiencies of 95.5% for La, 90.5% for Ce, 92.5% for Ti, and 60.8% for V within seven days. Beyond this period, efficiency decreased due to jarosite formation and microbial activity constraints. The findings confirm that bioleaching is a cost-effective and sustainable route that aligns with circular economy principles by reducing reliance on virgin rare earth mining while mitigating the environmental impact of catalyst disposal.